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Title: Palladium-Catalyzed Alkoxycarbonylation of Arylsulfoniums
Authors: Minami, Hiroko
Nogi, Keisuke
Yorimitsu, Hideki
Author's alias: 南, 裕子
野木, 馨介
依光, 英樹
Issue Date: 19-Apr-2019
Publisher: American Chemical Society
Journal title: Organic Letters
Volume: 21
Issue: 8
Start page: 2518
End page: 2522
Abstract: Alkoxycarbonylation of arylsulfoniums has been developed with the aid of a catalytic amount of a palladium-Xantphos complex under an atmospheric pressure of CO gas. Various functional groups such as carbonyl, cyano, halo, and sulfonyl groups were well tolerated under the present catalysis. Since aryldimethylsulfoniums were readily prepared from the corresponding aryl methyl sulfides and methyl triflate, one-pot alkoxycarbonylation of aryl methyl sulfides could be accomplished.
Rights: This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
DOI(Published Version): 10.1021/acs.orglett.9b00067
PubMed ID: 30938159
Appears in Collections:Journal Articles

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