ダウンロード数: 288
このアイテムのファイル:
ファイル | 記述 | サイズ | フォーマット | |
---|---|---|---|---|
bcsj.20180356.pdf | 625.35 kB | Adobe PDF | 見る/開く |
タイトル: | Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate |
著者: | Kise, Ryuma Fukumi, Aki Shioya, Nobutaka https://orcid.org/0000-0002-2915-894X (unconfirmed) Shimoaka, Takafumi https://orcid.org/0000-0001-9131-9831 (unconfirmed) Sonoyama, Masashi Amii, Hideki Takagi, Toshiyuki Kanamori, Toshiyuki Eda, Kazuo Hasegawa, Takeshi https://orcid.org/0000-0001-5574-9869 (unconfirmed) |
著者名の別形: | 黄瀬, 隆磨 塩谷, 暢貴 下赤, 卓史 長谷川, 健 |
キーワード: | Short perfluoroalkyl-containing compound Self-assembled monolayer technique Fluorous surface property |
発行日: | 19-Jan-2019 |
出版者: | Chemical Society of Japan |
誌名: | Bulletin of the Chemical Society of Japan |
巻: | 92 |
号: | 4 |
開始ページ: | 785 |
終了ページ: | 789 |
抄録: | Fluorous properties represented by water-and-oil repellency are perfluoroalkyl (Rf) compound-specific characteristics, which are widely used for surface coating of glass, electronic devices and textiles for preventing water and grease fouling. According to the stratified dipole-arrays (SDA) theory, the minimum Rf length of (CF₂)₇ is theoretically necessary for realizing fluorous properties. Unfortunately, however, production of compounds involving this chemical unit is strictly banned because of concerns of environmental pollution, which is a big dilemma. Here, we show that the fluorous properties can be realized by self-assembled monolayer (SAM) even with a short Rf-containing compound, since the SAM technique makes the best use of the self-aggregation property of the Rf groups, and it readily makes the molecules immobile. |
著作権等: | © 2019 The Chemical Society of Japan 発行元の許可を得て登録しています. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/241217 |
DOI(出版社版): | 10.1246/bcsj.20180356 |
出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。