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タイトル: | Total Synthesis of (+)-Conolidine by the Gold(I)-Catalyzed Cascade Cyclization of a Conjugated Enyne |
著者: | Naoe, Saori Yoshida, Yusuke Oishi, Shinya https://orcid.org/0000-0002-2833-2539 (unconfirmed) Fujii, Nobutaka Ohno, Hiroaki https://orcid.org/0000-0002-3246-4809 (unconfirmed) |
著者名の別形: | 大石, 真也 藤井, 信孝 大野, 浩章 |
発行日: | Jul-2016 |
出版者: | American Chemical Society (ACS) |
誌名: | The Journal of Organic Chemistry |
巻: | 81 |
号: | 13 |
開始ページ: | 5690 |
終了ページ: | 5698 |
抄録: | A total synthesis of (+)-conolidine has been achieved via the gold(I)-catalyzed cascade cyclization of a conjugated enyne. Remarkably, this strategy allowed for the simultaneous formation of the indole ring and the ethylidene-substituted piperidine moiety of (+)-conolidine under homogeneous gold catalysis in an enantioselective manner (88–91% ee). |
著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'The Journal of Organic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.6b00720. The full-text file will be made open to the public on 8 June 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/241631 |
DOI(出版社版): | 10.1021/acs.joc.6b00720 |
PubMed ID: | 27276227 |
出現コレクション: | 学術雑誌掲載論文等 |
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