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Title: Total Synthesis of (+)-Conolidine by the Gold(I)-Catalyzed Cascade Cyclization of a Conjugated Enyne
Authors: Naoe, Saori
Yoshida, Yusuke
Oishi, Shinya
Fujii, Nobutaka
Ohno, Hiroaki
Author's alias: 大石, 真也
藤井, 信孝
大野, 浩章
Issue Date: Jul-2016
Publisher: American Chemical Society (ACS)
Journal title: The Journal of Organic Chemistry
Volume: 81
Issue: 13
Start page: 5690
End page: 5698
Abstract: A total synthesis of (+)-conolidine has been achieved via the gold(I)-catalyzed cascade cyclization of a conjugated enyne. Remarkably, this strategy allowed for the simultaneous formation of the indole ring and the ethylidene-substituted piperidine moiety of (+)-conolidine under homogeneous gold catalysis in an enantioselective manner (88–91% ee).
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'The Journal of Organic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.6b00720.
The full-text file will be made open to the public on 8 June 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/241631
DOI(Published Version): 10.1021/acs.joc.6b00720
PubMed ID: 27276227
Appears in Collections:Journal Articles

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