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Title: Catalytic Asymmetric Synthesis of anti-α,β-Diamino Acid Derivatives
Authors: Izumi, Sanae
Kobayashi, Yusuke
Takemoto, Yoshiji
Author's alias: 泉, 早苗
小林, 祐輔
竹本, 佳司
Issue Date: 19-Feb-2016
Publisher: American Chemical Society (ACS)
Journal title: Organic Letters
Volume: 18
Issue: 4
Start page: 696
End page: 699
Abstract: A novel approach to chiral anti-α, β-diamino acid derivatives through tandem orthogonal organocatalysis has been developed. Chiral phosphoric acid catalysts control the chemo-, regio-, and stereoselective addition of hydroxylamines to alkylideneoxazolones, while a phosphine catalyst promotes the isomerization of Z- alkylideneoxazolones to the more reactive E- alkylideneoxazolones. (Chemical Equation Presented).
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Organic Letters', copyright © 2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
DOI(Published Version): 10.1021/acs.orglett.5b03666
PubMed ID: 26859161
Appears in Collections:Journal Articles

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