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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| fchem.2019.00430.pdf | 2.35 MB | Adobe PDF | 見る/開く |
| タイトル: | Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates |
| 著者: | Fujihara, Tetsuaki    https://orcid.org/0000-0002-6687-2528 (unconfirmed)Tsuji, Yasushi |
| 著者名の別形: | 藤原, 哲晶 辻, 康之 |
| キーワード: | carbon dioxide carboxylic acids allyl metals transmetalation oxidative addition addition reactions |
| 発行日: | 27-Jun-2019 |
| 出版者: | Frontiers Media SA |
| 誌名: | Frontiers in Chemistry |
| 巻: | 7 |
| 論文番号: | 430 |
| 抄録: | The use of carbon dioxide (CO2) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO2 are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of organic substrates with CO2 via allyl metal intermediates. First, carboxylation reactions via transmetalation are reviewed. Second, catalytic carboxylation reactions using allyl electrophiles and suitable reducing agents are summarized. The last section discusses the catalytic carboxylation reactions via addition reactions, affording allyl metal intermediates. |
| 著作権等: | © 2019 Fujihara and Tsuji. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
| URI: | http://hdl.handle.net/2433/243000 |
| DOI(出版社版): | 10.3389/fchem.2019.00430 |
| PubMed ID: | 31316967 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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