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タイトル: | Alternating Sequence Control for Carboxylic Acid and Hydroxy Pendant Groups by Controlled Radical Cyclopolymerization of a Divinyl Monomer Carrying a Cleavable Spacer |
著者: | Ouchi, Makoto ![]() ![]() ![]() Nakano, Marina Nakanishi, Tomoya Sawamoto, Mitsuo |
著者名の別形: | 大内, 誠 中野, 麻里奈 中西, 智哉 澤本, 光男 |
キーワード: | Cyclopolymerisationen Methacrylsäure Radikalische Polymerizationen Sequenzkontrolle Untere kritische Lösungstemperatur (LCST) |
発行日: | 11-Nov-2016 |
出版者: | Wiley |
誌名: | Angewandte Chemie |
巻: | 55 |
号: | 47 |
開始ページ: | 14584 |
終了ページ: | 14589 |
抄録: | By utilizing features of the hemiacetal ester (HAE) bond: easy formation from vinyl ether and carboxylic acid and easy cleavage into different functional groups (‐COOH and ‐OH), we achieved control of the alternating sequence of two functional pendant groups of a vinyl copolymer. Methacrylate‐ and acrylate‐based vinyl groups were connected through HAE bonds to prepare a cleavable divinyl monomer, which was cyclo‐polymerized under optimized conditions in a ruthenium‐catalyzed living radical polymerization. Subsequent cleavage of the HAE bonds in the resultant cyclo‐pendant led to a copolymer consisting of alternating methacrylic acid and 2‐hydroxyethyl acrylate units as analyzed by ¹³C NMR spectroscopy. The alternating sequence of ‐COOH and ‐OH pendants specifically provided a lower critical solution temperature (LCST) in an ether solvent, which was not observed with the random copolymer of same composition ratio. |
著作権等: | This is the peer reviewed version of the following article: M. Ouchi, M. Nakano, T. Nakanishi, M. Sawamoto, Angew. Chem. 2016, 128, 14804., which has been published in final form at https://doi.org/10.1002/ange.201607169. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/243222 |
DOI(出版社版): | 10.1002/anie.201607169 |
PubMed ID: | 27761985 |
出現コレクション: | 学術雑誌掲載論文等 |

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