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タイトル: | A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra |
著者: | Carné-Sánchez, Arnau Craig, Gavin A. Larpent, Patrick Guillerm, Vincent Urayama, Kenji ![]() ![]() ![]() Maspoch, Daniel Furukawa, Shuhei ![]() ![]() ![]() |
著者名の別形: | カルネサンチェス, アルナウ クレイグ, ガビン 浦山, 健治 古川, 修平 |
キーワード: | coordination cages metal–organic polyhedra microporous materials polymers supramolecular chemistry |
発行日: | 6-May-2019 |
出版者: | Wiley |
誌名: | Angewandte Chemie International Edition |
巻: | 58 |
号: | 19 |
開始ページ: | 6347 |
終了ページ: | 6350 |
抄録: | Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining solubility often requires covalently bound functional groups that are unnecessary for porosity and which ultimately occupy free volume in the materials, decreasing their surface areas. Here, a method is described that takes advantage of the coordination bonds in metal–organic polyhedra (MOPs) to render insoluble MOPs soluble by reversibly attaching an alkyl‐functionalized ligand. We then use the newly soluble MOPs as monomers for supramolecular polymerization reactions, obtaining permanently porous, amorphous polymers with the shape of colloids and gels, which display increased gas uptake in comparison with materials made with covalently functionalized MOPs. |
著作権等: | © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
URI: | http://hdl.handle.net/2433/243550 |
DOI(出版社版): | 10.1002/anie.201901668 |
PubMed ID: | 30848051 |
出現コレクション: | 学術雑誌掲載論文等 |
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