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dc.contributor.author | Carné-Sánchez, Arnau | en |
dc.contributor.author | Craig, Gavin A. | en |
dc.contributor.author | Larpent, Patrick | en |
dc.contributor.author | Guillerm, Vincent | en |
dc.contributor.author | Urayama, Kenji | en |
dc.contributor.author | Maspoch, Daniel | en |
dc.contributor.author | Furukawa, Shuhei | en |
dc.contributor.alternative | カルネサンチェス, アルナウ | ja |
dc.contributor.alternative | クレイグ, ガビン | ja |
dc.contributor.alternative | 浦山, 健治 | ja |
dc.contributor.alternative | 古川, 修平 | ja |
dc.date.accessioned | 2019-08-22T05:04:09Z | - |
dc.date.available | 2019-08-22T05:04:09Z | - |
dc.date.issued | 2019-05-06 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2433/243550 | - |
dc.description.abstract | Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining solubility often requires covalently bound functional groups that are unnecessary for porosity and which ultimately occupy free volume in the materials, decreasing their surface areas. Here, a method is described that takes advantage of the coordination bonds in metal–organic polyhedra (MOPs) to render insoluble MOPs soluble by reversibly attaching an alkyl‐functionalized ligand. We then use the newly soluble MOPs as monomers for supramolecular polymerization reactions, obtaining permanently porous, amorphous polymers with the shape of colloids and gels, which display increased gas uptake in comparison with materials made with covalently functionalized MOPs. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley | en |
dc.rights | © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. | en |
dc.subject | coordination cages | en |
dc.subject | metal–organic polyhedra | en |
dc.subject | microporous materials | en |
dc.subject | polymers | en |
dc.subject | supramolecular chemistry | en |
dc.title | A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Angewandte Chemie International Edition | en |
dc.identifier.volume | 58 | - |
dc.identifier.issue | 19 | - |
dc.identifier.spage | 6347 | - |
dc.identifier.epage | 6350 | - |
dc.relation.doi | 10.1002/anie.201901668 | - |
dc.textversion | publisher | - |
dc.identifier.pmid | 30848051 | - |
dcterms.accessRights | open access | - |
datacite.awardNumber | 18H01995 | - |
datacite.awardNumber | 17H05367 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
出現コレクション: | 学術雑誌掲載論文等 |
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