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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| s-0037-1611869.pdf | 401.67 kB | Adobe PDF | 見る/開く |
| タイトル: | Copper-Catalyzed Twofold Silylmetalation of Alkynes |
| 著者: | Yamagishi, Hiroki Shimokawa, Jun    https://orcid.org/0000-0002-4023-4640 (unconfirmed)Yorimitsu, Hideki https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 山岸, 拓幹 下川, 淳 依光, 英樹 |
| キーワード: | silylmetalation disilane copper catalysis ate complex disilyldiarylethanes |
| 発行日: | 2019 |
| 出版者: | Georg Thieme Verlag |
| 誌名: | Synlett |
| 巻: | 30 |
| 号: | 13 |
| 開始ページ: | 1551 |
| 終了ページ: | 1554 |
| 抄録: | The first twofold silylmetalation across a C≡C triple bond was achieved. In the presence of a catalytic amount of copper cyanide, diarylacetylenes were converted into 1, 2-dimetalated 1, 2-disilyl-1, 2-diarylethanes on treatment with silylpotassium species generated in situ from disilane and t-BuOK. The dimetalated species were subsequently protonated to yield a series of 1, 2-disilyl-1, 2-diarylethanes. |
| 著作権等: | This is the accepted manuscript of the article, which has been published at https://doi.org/10.1055/s-0037-1611869. The full-text file will be made open to the public on 25 June 2020 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/243797 |
| DOI(出版社版): | 10.1055/s-0037-1611869 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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