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タイトル: | Single crystal synthesis and magnetic properties of Co²⁺-substituted and non-substituted magnetoplumbite-type Na–La ferrite |
著者: | Waki, Takeshi Takao, Kenta Tabata, Yoshikazu ![]() ![]() Nakamura, Hiroyuki ![]() ![]() |
著者名の別形: | 和氣, 剛 高尾, 健太 田畑, 吉計 中村, 裕之 |
キーワード: | Magnetoplumbite-type Na-La ferrite Magnetocrystalline anisotropy Ferrite magnet Single crystal |
発行日: | Feb-2020 |
出版者: | Elsevier BV |
誌名: | Journal of Solid State Chemistry |
巻: | 282 |
論文番号: | 121071 |
抄録: | Single crystals of magnetoplumbite-type Na–La ferrite with and without Co doping were grown by the flux method. Wave length dispersive X-ray analysis reveals that Na and La are present in the ratio of Na/La = 0.25–0.41, and Co is successfully substituted for Fe. Magnetization measurements using single crystals indicate uniaxial magnetic anisotropy in these materials. A metamagnetic transition for the hard-axis magnetization was observed in non Co²⁺-substituted samples at around 7 kOe due to the magnetic free energy double minima originating from the Fe²⁺ ion. The successful introduction of Co²⁺ enhances the uniaxial magnetic anisotropy favorable for permanent magnets. |
著作権等: | © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. The full-text file will be made open to the public on 1 February 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/245250 |
DOI(出版社版): | 10.1016/j.jssc.2019.121071 |
出現コレクション: | 学術雑誌掲載論文等 |

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