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タイトル: Single crystal synthesis and magnetic properties of Co²⁺-substituted and non-substituted magnetoplumbite-type Na–La ferrite
著者: Waki, Takeshi
Takao, Kenta
Tabata, Yoshikazu  kyouindb  KAKEN_id
Nakamura, Hiroyuki  kyouindb  KAKEN_id
著者名の別形: 和氣, 剛
高尾, 健太
田畑, 吉計
中村, 裕之
キーワード: Magnetoplumbite-type Na-La ferrite
Magnetocrystalline anisotropy
Ferrite magnet
Single crystal
発行日: Feb-2020
出版者: Elsevier BV
誌名: Journal of Solid State Chemistry
巻: 282
論文番号: 121071
抄録: Single crystals of magnetoplumbite-type Na–La ferrite with and without Co doping were grown by the flux method. Wave length dispersive X-ray analysis reveals that Na and La are present in the ratio of Na/La ​= ​0.25–0.41, and Co is successfully substituted for Fe. Magnetization measurements using single crystals indicate uniaxial magnetic anisotropy in these materials. A metamagnetic transition for the hard-axis magnetization was observed in non Co²⁺-substituted samples at around 7 ​kOe due to the magnetic free energy double minima originating from the Fe²⁺ ion. The successful introduction of Co²⁺ enhances the uniaxial magnetic anisotropy favorable for permanent magnets.
著作権等: © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/.
The full-text file will be made open to the public on 1 February 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
This is not the published version. Please cite only the published version.
URI: http://hdl.handle.net/2433/245250
DOI(出版社版): 10.1016/j.jssc.2019.121071
出現コレクション:学術雑誌掲載論文等

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