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j.jfluchem.2006.10.016.pdf | 389.24 kB | Adobe PDF | 見る/開く |
タイトル: | Structural characteristics of alkylimidazolium-based salts containing fluoroanions |
著者: | Matsumoto, Kazuhiko https://orcid.org/0000-0002-0770-9210 (unconfirmed) Hagiwara, Rika https://orcid.org/0000-0002-7234-3980 (unconfirmed) |
著者名の別形: | 松本, 一彦 萩原, 理加 |
キーワード: | Ionic liquid Structure Room temperature molten salt Fluoroanion Alkylimidazolium |
発行日: | Apr-2007 |
出版者: | Elsevier BV |
誌名: | Journal of Fluorine Chemistry |
巻: | 128 |
号: | 4 |
開始ページ: | 317 |
終了ページ: | 331 |
抄録: | An overview of recent structural studies on alkylimidazolium-based salts containing fluoroanions is presented. Alkylimidazolium cations have been most extensively used for syntheses of ionic liquids (room temperature molten salts) because they usually exhibit low melting points, low viscosities and high conductivities. This review mainly focuses on structures of alkylimidazolium-based salts combined with a fluorocomplex anion ((FH)nF⁻, BF₄⁻, PF₆⁻, AsF₆⁻, SbF₆⁻, NbF₆⁻, TaF₆⁻), N(SO₂CF3)₂⁻ (TFSI⁻) and OSO₂CF₃⁻. The first part describes crystal structures of these salts and the second part describes computational, spectroscopic and diffraction studies on their liquid structures. Related studies on ionic liquids of non-alkylimidazolium cation and non-fluoroanion are also briefly summarized. |
著作権等: | © 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 1 April 2009 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/251199 |
DOI(出版社版): | 10.1016/j.jfluchem.2006.10.016 |
出現コレクション: | 学術雑誌掲載論文等 |
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