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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| jacs.0c04598.pdf | 2.38 MB | Adobe PDF | 見る/開く |
| タイトル: | Anti-Markovnikov Hydroamination of Alkenes with Aqueous Ammonia by Metal-Loaded Titanium Oxide Photocatalyst |
| 著者: | Park, Soyeong Jeong, Jaeyoung Fujita, Ken-ichi    https://orcid.org/0000-0002-8362-2694 (unconfirmed)Yamamoto, Akira https://orcid.org/0000-0002-1329-0807 (unconfirmed)Yoshida, Hisao https://orcid.org/0000-0002-2540-0225 (unconfirmed) |
| 著者名の別形: | 朴, 素暎 丁, 在瑛 藤田, 健一 山本, 旭 吉田, 寿雄 |
| キーワード: | Colloid and Surface Chemistry Biochemistry General Chemistry Catalysis |
| 発行日: | 22-Jul-2020 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Journal of the American Chemical Society |
| 巻: | 142 |
| 号: | 29 |
| 開始ページ: | 12708 |
| 終了ページ: | 12714 |
| 抄録: | A completely new route was established to synthesize valuable primary amines from alkenes by using aqueous ammonia, that is, a simple photocatalytic hydroamination of alkenes using aqueous ammonia with a metal-loaded TiO2 photocatalyst. Although the photochemical hydroamination prefers to form amines according to the Markovnikov rule, the new photocatalytic hydroamination gives anti-Markovnikov products predominantly. With an Au-loaded TiO2 photocatalyst, the amine yield reached up to 93% and the regioselectivity of anti-Markovnikov products was above 98%. The reaction mechanism was proposed for the new photocatalytic hydroamination. |
| 記述: | 光触媒による第一級アミンの新合成ルートを確立 --アンモニア水を窒素源とする直接合成法の開発--. 京都大学プレスリリース. 2020-07-10. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Journal of the American Chemical Society', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.0c04598. The full-text file will be made open to the public on 22 June 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving' この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/253574 |
| DOI(出版社版): | 10.1021/jacs.0c04598 |
| PubMed ID: | 32568530 |
| 関連リンク: | https://www.kyoto-u.ac.jp/ja/research-news/2020-07-10-0 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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