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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| bjoc.16.86.pdf | 1.78 MB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes |
| 著者: | Yoshimura, Aya Kimura, Hitoshi Kagawa, Kohei Yoshioka, Mayuka Itou, Toshiki Vasu, Dhananjayan Shirahata, Takashi Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed)Misaki, Yohji |
| 著者名の別形: | 吉村, 彩 木村, 仁 賀川, 恒平 伊藤, 俊基 白旗, 崇 依光, 英樹 御崎, 洋二 |
| キーワード: | cross-conjugated systems electrochemical properties extended π-conjugation digital simulation analysis tetrathiafulvalene |
| 発行日: | 2020 |
| 出版者: | Beilstein Institut |
| 誌名: | Beilstein Journal of Organic Chemistry |
| 巻: | 16 |
| 開始ページ: | 974 |
| 終了ページ: | 981 |
| 抄録: | Novel multistage redox tetrathiafulvalenes (TTFs) bearing 6-aryl-1, 4-dithiafulvene moieties were synthesized by palladium-catalyzed direct C–H arylation. In the presence of a catalytic amount of Pd(OAc)2, P(t-Bu3)·HBF4, and an excess of Cs2CO3, the C–H arylation of TTF with several aryl bromides bearing 1, 3-dithiol-2-ylidenes took place efficiently to produce the corresponding π-conjugated molecules. We also succeeded in the estimation of the oxidation potentials and number of electrons involved in each oxidation step of the obtained compounds by digital simulations. |
| 著作権等: | © 2020 Yoshimura et al.; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc) |
| URI: | http://hdl.handle.net/2433/253868 |
| DOI(出版社版): | 10.3762/bjoc.16.86 |
| PubMed ID: | 32509028 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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