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タイトル: Development Perspective of Bioelectrocatalysis-Based Biosensors
著者: Adachi, Taiki  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-3863-993X (unconfirmed)
Kitazumi, Yuki  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-6171-6457 (unconfirmed)
Shirai, Osamu
Kano, Kenji
著者名の別形: 足立, 大宜
北隅, 優希
白井, 理
加納, 健司
キーワード: current–potential curve
multi-enzymatic cascades
multianalyte detection
mass-transfer-controlled amperometric response
potentiometric coulometry
発行日: 1-Sep-2020
出版者: MDPI AG
誌名: Sensors
巻: 20
号: 17
論文番号: 4826
抄録: Bioelectrocatalysis provides the intrinsic catalytic functions of redox enzymes to nonspecific electrode reactions and is the most important and basic concept for electrochemical biosensors. This review starts by describing fundamental characteristics of bioelectrocatalytic reactions in mediated and direct electron transfer types from a theoretical viewpoint and summarizes amperometric biosensors based on multi-enzymatic cascades and for multianalyte detection. The review also introduces prospective aspects of two new concepts of biosensors: mass-transfer-controlled (pseudo)steady-state amperometry at microelectrodes with enhanced enzymatic activity without calibration curves and potentiometric coulometry at enzyme/mediator-immobilized biosensors for absolute determination.
著作権等: © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
URI: http://hdl.handle.net/2433/255254
DOI(出版社版): 10.3390/s20174826
PubMed ID: 32858975
出現コレクション:学術雑誌掲載論文等

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