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Title: Stability of a boron-doped diamond electrode in molten chloride systems
Authors: Kado, Yuya
Goto, Takuya
Hagiwara, Rika  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-7234-3980 (unconfirmed)
Author's alias: 加登, 裕也
後藤, 琢也
萩原, 理加
Keywords: Inert anode
Boron-doped diamond electrode
Oxygen evolution
Molten alkali chlorides
Issue Date: Sep-2009
Publisher: Elsevier BV
Journal title: Diamond and Related Materials
Volume: 18
Issue: 9
Start page: 1186
End page: 1190
Abstract: Stability of a boron-doped diamond as an oxygen evolution electrode material was evaluated at 773 K in molten LiCl–KCl (58.5:41.5 mol%), LiCl–KCl (75:25 mol%), LiCl–CaCl₂ (64:36 mol%), LiCl–NaCl–CaCl₂ (52.3:13.5:34.2 mol%). In molten LiCl–KCl systems, the BDD is stable at 773 K regardless of the concentration of oxide ion and the composition of the melt. In molten LiCl–CaCl₂ and LiCl–NaCl–CaCl₂, the BDD electrode is less stable than in molten LiCl–KCl systems.
Rights: © 2009. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/255609
DOI(Published Version): 10.1016/j.diamond.2009.03.006
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