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dc.contributor.authorKado, Yuya
dc.contributor.authorGoto, Takuya
dc.contributor.authorHagiwara, Rika
dc.contributor.alternative加登, 裕也
dc.contributor.alternative後藤, 琢也
dc.contributor.alternative萩原, 理加
dc.date.accessioned2020-10-20T06:58:23Z-
dc.date.available2020-10-20T06:58:23Z-
dc.date.issued2009
dc.identifier.issn0013-4651
dc.identifier.urihttp://hdl.handle.net/2433/255613-
dc.description.abstractOxygen electrode reaction was investigated on a boron-doped diamond electrode in a LiCl–KCl eutectic melt. The standard formal potential of O₂/O²⁻ decreases with the elevation of temperature. The potential at 773 K is 2.424 ± 0.003 V vs Li⁺/ Li. The standard formal free energy change increases with the temperature elevation, calculated to be -456.4 ± 0.5 kJ mol⁻¹ at 773 K. The standard formal entropy and enthalpy changes are determined to be -151 ± 3 J K⁻¹ mol⁻¹ and -573.5 ± 0.1 kJ mol⁻¹, respectively, at 773 K.
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherThe Electrochemical Society
dc.rightsThis is the Accepted Manuscript version of an article accepted for publication in Journal of The Electrochemical Society. The Electrochemical Society and IOP Publishing Ltd are not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/1.3212844.
dc.rightsThis is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
dc.titleOxygen Electrode Reaction in a LiCl–KCl Eutectic Melt
dc.type.niitypeJournal Article
dc.identifier.jtitleJournal of The Electrochemical Society
dc.identifier.volume156
dc.relation.doi10.1149/1.3212844
dc.textversionauthor
dc.identifier.artnumE167
dc.addressDepartment of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University
dc.addressDepartment of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University
dc.addressDepartment of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University
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