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| j.jct.2010.04.023.pdf | 367.87 kB | Adobe PDF | 見る/開く |
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| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Kado, Yuya | en |
| dc.contributor.author | Goto, Takuya | en |
| dc.contributor.author | Hagiwara, Rika | en |
| dc.contributor.alternative | 加登, 裕也 | ja |
| dc.contributor.alternative | 後藤, 琢也 | ja |
| dc.contributor.alternative | 萩原, 理加 | ja |
| dc.date.accessioned | 2020-10-20T07:15:11Z | - |
| dc.date.available | 2020-10-20T07:15:11Z | - |
| dc.date.issued | 2010-10 | - |
| dc.identifier.issn | 0021-9614 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/255614 | - |
| dc.description.abstract | Activity coefficients of oxide ion were determined by the measurements of the standard formal potential of O₂/O²⁻ with a boron-doped diamond (BDD) electrode in molten (LiCl + KCl): LiCl:KCl = {58.5:41.5 (eutectic), 65:35, 70:30, 75:25} mol% at T = (673 to 803) K. The activity coefficient decreases with the increase of the LiCl content in the melt: (18.7 ± 1.5, 7.7 ± 1.0, 4.1 ± 0.4, and 1.6 ± 0.1), respectively, at T = 773 K in each melt. The result is explained by the attractive force between Li⁺ and O²⁻ which is stronger than that between K⁺ and O²⁻. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Elsevier BV | en |
| dc.rights | © 2010. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. | en |
| dc.rights | This is not the published version. Please cite only the published version. | en |
| dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
| dc.subject | LiCl–KCl | en |
| dc.subject | Boron-doped diamond electrode | en |
| dc.subject | Oxygen evolution | en |
| dc.subject | O₂/O²⁻ potential | en |
| dc.subject | Activity coefficient | en |
| dc.title | Thermodynamics of the O₂/O²⁻ redox couple in molten (LiCl+KCl+Li₂O) systems | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | The Journal of Chemical Thermodynamics | - |
| dc.identifier.volume | 42 | - |
| dc.identifier.issue | 10 | - |
| dc.identifier.spage | 1230 | - |
| dc.identifier.epage | 1233 | - |
| dc.relation.doi | 10.1016/j.jct.2010.04.023 | - |
| dc.textversion | author | - |
| dc.address | Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University | en |
| dc.address | Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University | en |
| dc.address | Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University | en |
| dcterms.accessRights | open access | - |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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