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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| j.electacta.2020.136289.pdf | 4.28 MB | Adobe PDF | 見る/開く |
| タイトル: | Electrodeposition of an iron thin film with compact and smooth morphology using an ethereal electrolyte |
| 著者: | Zhang, Zelei Kitada, Atsushi   https://orcid.org/0000-0002-4387-8687 (unconfirmed)Fukami, Kazuhiro  https://orcid.org/0000-0001-9120-5578 (unconfirmed)Yao, Zhengjun Murase, Kuniaki https://orcid.org/0000-0002-7564-9416 (unconfirmed) |
| 著者名の別形: | 張, 澤磊 北田, 敦 深見, 一弘 邑瀬, 邦明 |
| キーワード: | Iron electrodeposition Surface morphology Thin film Nucleation mechanism Ethereal electrolyte |
| 発行日: | 10-Jul-2020 |
| 出版者: | Elsevier BV |
| 誌名: | Electrochimica Acta |
| 巻: | 348 |
| 論文番号: | 136289 |
| 抄録: | Electrodeposition of iron (Fe) from an ethereal solution was investigated. The bath consisted of ferrous chloride (FeCl₂), diglyme (G2), and aluminum chloride (AlCl₃), in which iron species were estimated to be [Fe(G2)₂]²⁺ complex cations. The effect of hydrogen gas evolution on the morphology of iron deposits was determined by comparing common aqueous electrolytes. An Fe thin film was fabricated using the FeCl₂–G2–AlCl₃ bath without the influence of hydrogen gas evolution, and the nucleation of Fe was explained by an instantaneous nucleation mechanism. As a result, the surface morphology of the Fe thin film was compact and smooth compared with the cases of aqueous and other nonaqueous electrolytes. |
| 著作権等: | © 2020 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
| URI: | http://hdl.handle.net/2433/255858 |
| DOI(出版社版): | 10.1016/j.electacta.2020.136289 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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