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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 09810.0393ecst.pdf | 891.7 kB | Adobe PDF | 見る/開く |
| タイトル: | Optimization of electrolysis conditions for ti film electrodeposition from lif-licl eutectic molten salt |
| 著者: | Unoki, Makoto Norikawa, Yutaro    https://orcid.org/0000-0002-0861-5443 (unconfirmed)Yasuda, Kouji Nohira, Toshiyuki |
| 著者名の別形: | 鵜木, 亮 法川, 勇太郎 安田, 幸司 野平, 俊之 |
| 発行日: | 2020 |
| 出版者: | IOP Publishing Ltd |
| 誌名: | ECS Transactions |
| 巻: | 98 |
| 号: | 10 |
| 開始ページ: | 393 |
| 終了ページ: | 400 |
| 抄録: | The optimum conditions for electrodepositing compact, smooth, and adherent Ti films in LiF–LiCl–Li₃TiF₆ at 823 K were investigated. The Li₃TiF₆ was formed in-situ in the melt via comproportionation reaction between Li₂TiF₆ and Ti powder. The solubility of Li₃TiF₆ was confirmed to be higher than 7.1 mol% by cyclic voltammetry and ICP-AES measurement. Galvanostatic electrolysis was conducted on Ni plate substrates at various concentrations of Li₃TiF₆ (0.55, 2.6, 7.1 mol%) and cathodic current density (50–1200 mA cm⁻²). Ti films with smoother surface were obtained at higher Li₃TiF₆ concentration and lower current density. In the present study, Ti films having the smoothest surface were obtained at 7.1 mol% of Li₃TiF₆ and 50 mA cm⁻². |
| 記述: | PRiME 2020, Honolulu, USA, October 4-9, 2020. |
| 著作権等: | This is the Accepted Manuscript version of an article accepted for publication in ECS Transactions. The Electrochemical Society and IOP Publishing Ltd are not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/09810.0393ecst. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/255865 |
| DOI(出版社版): | 10.1149/09810.0393ecst |
| 出現コレクション: | 学術雑誌掲載論文等 |
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