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このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 09810.0471ecst.pdf | 1 MB | Adobe PDF | 見る/開く |
| タイトル: | Ammonium·18-crown-6 bis(trifluoromethylsulfonyl)amide |
| 著者: | Kawata, Kio Kitada, Atsushi Fukami, Kazuhiro    https://orcid.org/0000-0001-9120-5578 (unconfirmed)Murase, Kuniaki https://orcid.org/0000-0002-7564-9416 (unconfirmed) |
| 著者名の別形: | 川田, 稀士 北田, 敦 深見, 一弘 邑瀬, 邦明 |
| 発行日: | 2020 |
| 出版者: | IOP Publishing Ltd |
| 誌名: | ECS Transactions |
| 巻: | 98 |
| 号: | 10 |
| 開始ページ: | 471 |
| 終了ページ: | 475 |
| 抄録: | We report synthesis and characterization of an ammonium-based molten salt, ammonium bis(trifluoromethylsulfonyl)amide-18-crown-6 (1/1), i.e. [NH₄⁺･18C6][Tf₂N⁻] (Tf = SO₂CF₃). Raman spectra shows [NH₄⁺･18C6][Tf₂N⁻] consists of NH₄⁺ ion encapsulated by 18C6 and Tf₂N⁻ anion. The melting point of [NH₄⁺･18C6][Tf₂N⁻] was around 100°C. At 140°C, the viscosity of [NH₄⁺･18C6][Tf₂N⁻] was 14.7 mPa s, the conductivity was 8.0 mS cm⁻¹, and the density was 1.23 g cm⁻³. These properties were comparable to those of common ionic liquids. |
| 著作権等: | This is the Accepted Manuscript version of an article accepted for publication in ECS Transactions. The Electrochemical Society and IOP Publishing Ltd are not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/09810.0471ecst. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/255873 |
| DOI(出版社版): | 10.1149/09810.0471ecst |
| 出現コレクション: | 学術雑誌掲載論文等 |
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