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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 1.3117215.pdf | 477.08 kB | Adobe PDF | 見る/開く |
| タイトル: | Room-Temperature Fluorohydrogenate Ionic Liquids of Alkylpyridinium Cations and Allylated Quarternary Cyclic Ammonium Cations |
| 著者: | Yamagata, Masaki Konno, Soichiro Matsumoto, Kazuhiko    https://orcid.org/0000-0002-0770-9210 (unconfirmed)Hagiwara, Rika |
| 著者名の別形: | 山縣, 雅紀 松本, 一彦 萩原, 理加 |
| 発行日: | Jan-2009 |
| 出版者: | Electrochemical Society |
| 誌名: | Electrochemical and Solid-State Letters |
| 巻: | 12 |
| 号: | 7 |
| 論文番号: | F9 |
| 抄録: | A series of fluorohydrogenate ionic liquids (FHILs), Cat⁺(FH)₂.₃F⁻(Cat⁺: alkylpyridinium cations and allylated quarternary cyclic ammonium cations), are prepared, and their physical and electrochemical properties are characterized. The viscosities and conductivities of alkylpyridinium-based FHILs increase and decrease, respectively, with an increase in the length of the side chain. The FHILs of allylated cations exhibit higher ionic conductivities than those of the corresponding propylated cations and even those of the ethylated cations in some cases, which is explained by differences in volume, charge distribution, and rotational freedom of the side chains according to quantum mechanical calculations. The electrochemical windows of the FHILs are around 4 V. |
| 著作権等: | This is the Accepted Manuscript version of an article accepted for publication in Electrochemical and Solid-State Letters. The Electrochemical Society and IOP Publishing Ltd are not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/1.3117215. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/261014 |
| DOI(出版社版): | 10.1149/1.3117215 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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