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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.0c03782.pdf | 691.97 kB | Adobe PDF | 見る/開く |
| タイトル: | Generation of Organozinc Reagents from Arylsulfonium Salts Using a Nickel Catalyst and Zinc Dust |
| 著者: | Yamada, Kodai Yanagi, Tomoyuki Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 山田, 航大 柳, 智征 依光, 英樹 |
| 発行日: | 18-Dec-2020 |
| 出版者: | American Chemical Society |
| 誌名: | Organic Letters |
| 巻: | 22 |
| 号: | 24 |
| 開始ページ: | 9712 |
| 終了ページ: | 9718 |
| 抄録: | Readily available aryldimethylsulfonium triflates react with zinc powder under nickel catalysis via the selective cleavage of the sp2-hybridized carbon–sulfur bond to produce salt-free arylzinc triflates under mild conditions. This zincation displays superb chemoselectivity and thus represents a protocol that is complementary or orthogonal to existing methods. The generated arylzinc reagents show both high reactivity and chemoselectivity in palladium-catalyzed and copper-mediated cross-coupling reactions. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c03782. The full-text file will be made open to the public on 10 December 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/261022 |
| DOI(出版社版): | 10.1021/acs.orglett.0c03782 |
| PubMed ID: | 33300805 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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