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Title: Pre-regulation of the planar chirality of pillar[5]arenes for preparing discrete chiral nanotubes
Authors: Fa, Shixin
Adachi, Keisuke
Nagata, Yuuya
Egami, Kouichi
Kato, Kenichi  kyouindb  KAKEN_id  orcid (unconfirmed)
Ogoshi, Tomoki  kyouindb  KAKEN_id  orcid (unconfirmed)
Author's alias: 足立, 佳祐
長田, 裕也
江上, 孝一
加藤, 研一
生越, 友樹
Issue Date: 14-Mar-2021
Publisher: Royal Society of Chemistry (RSC)
Journal title: Chemical Science
Volume: 12
Issue: 10
Start page: 3483
End page: 3488
Abstract: Regulating the chirality of macrocyclic host molecules and supramolecular assemblies is crucial because chirality often plays a role in governing the properties of these systems. Herein, we describe pillar[5]arene-based chiral nanotube formation via pre-regulation of the building blocks' chirality, which is different from frequently used post-regulation strategies. The planar chirality of rim-differentiated pillar[5]arenes is initially regulated by chiral awakening and further induction/inversion through stepwise achiral external stimuli. The pre-regulated chiral information is well stored in discrete nanotubes by interacting with a per-alkylamino-substituted pillar[5]arene. Such pre-regulation is more efficient than post-regulating the chirality of nanotubes.
Rights: © The Royal Society of Chemistry 2021. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
DOI(Published Version): 10.1039/d1sc00074h
Appears in Collections:Journal Articles

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