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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ajoc.202000688.pdf | 1.05 MB | Adobe PDF | 見る/開く |
| タイトル: | Five‐fold‐symmetric Pentabromo‐ and Pentaiodo‐corannulenes: Useful Precursors of Heteroatom‐substituted Corannulenes |
| 著者: | Kise, Koki Ooi, Shota Osuka, Atsuhiro Tanaka, Takayuki    https://orcid.org/0000-0001-8018-7984 (unconfirmed) |
| 著者名の別形: | 黄瀬, 光稀 大井, 翔太 大須賀, 篤弘 田中, 隆行 |
| キーワード: | corannulene halogenation phosphinylation X-ray crystallography |
| 発行日: | Mar-2021 |
| 出版者: | Wiley |
| 誌名: | Asian Journal of Organic Chemistry |
| 巻: | 10 |
| 号: | 3 |
| 開始ページ: | 537 |
| 終了ページ: | 540 |
| 抄録: | Five-fold-symmetric pentabromo- and pentaiodocorannulenes were synthesized in sub-gram scale in high yields under aerial conditions and were purified without any chromatographic separations. The obtained pentahalocorannulenes were fully characterized by NMR, MS, and X-ray crystallography. The pentahalocorannulenes are useful precursors of five-fold symmetric heteroatom-substituted corannulenes that are difficult-to-address from known corannulene derivatives. As a representative example, pentaphosphinylated corannulene was prepared for the first time and was comprehensively characterized. |
| 著作権等: | This is the peer reviewed version of the following article: [K. Kise, S. Ooi, A. Osuka, T. Tanaka, Asian J. Org. Chem. 2021, 10, 537.], which has been published in final form at https://doi.org/10.1002/ajoc.202000688. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. The full-text file will be made open to the public on 22 January 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/268313 |
| DOI(出版社版): | 10.1002/ajoc.202000688 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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