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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ajoc.202100206.pdf | 1.15 MB | Adobe PDF | 見る/開く |
| タイトル: | Defluorinative Diborasodiation of Benzotrifluorides with Bis(pinacolato)Diboron and Sodium |
| 著者: | Ito, Shiori Takahashi, Fumiya Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 伊藤, 詩織 高橋, 郁也 依光, 英樹 |
| キーワード: | reduction metalation borylation carbanion defluorination |
| 発行日: | Jun-2021 |
| 出版者: | Wiley |
| 誌名: | Asian Journal of Organic Chemistry |
| 巻: | 10 |
| 号: | 6 |
| 開始ページ: | 1440 |
| 終了ページ: | 1443 |
| 抄録: | Treatment of benzotrifluorides with sodium dispersion in the presence of bis(pinacolato)diboron results in diborative reduction to yield the corresponding diborylbenzylsodium species. The anionic species react not only with reactive organic halides but also with aromatic carbonyl compounds to yield the corresponding alkenylboron compounds via Peterson-type olefination. The success of the generation of the diborylbenzylsodium species lies in immediate capture of initially formed unstable difluorobenzylsodium with co-existing reduction-resistant bis(pinacolato)diboron. |
| 著作権等: | This is the peer reviewed version of the following article: [S. Ito, F. Takahashi, H. Yorimitsu, Asian J. Org. Chem. 2021, 10, 1440.], which has been published in final form at https://doi.org/10.1002/ajoc.202100206. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. The full-text file will be made open to the public on 29 April 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/268763 |
| DOI(出版社版): | 10.1002/ajoc.202100206 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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