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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.1c01355.pdf | 1.32 MB | Adobe PDF | 見る/開く |
| タイトル: | Sodium-Promoted Borylation of Polycyclic Aromatic Hydrocarbons |
| 著者: | Fukazawa, Mizuki Takahashi, Fumiya Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 深澤, 瑞喜 高橋, 郁也 依光, 英樹 |
| キーワード: | Redox reactions Hydrocarbons Borylation Anions Aromatic compounds reduction metalation boration |
| 発行日: | Jun-2021 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Organic Letters |
| 巻: | 23 |
| 号: | 12 |
| 開始ページ: | 4613 |
| 終了ページ: | 4617 |
| 抄録: | Sodium dispersion promotes the reductive borylation of polycyclic aromatic hydrocarbons (PAHs) with MeOBpin. Anthracenes and phenanthrenes are converted to the corresponding dearomatized diborylated products. The reductive diborylation of naphthalene-based small π-systems yields similar yet unstable products that are oxidized into formal C–H borylation products with unique regioselectivity. Pyrene is converted to 1-borylpyrene without the addition of an oxidant. The latter two reactions represent a new route to useful borylated PAHs that rivals C–X borylation and catalytic C–H borylation. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.1c01355. The full-text file will be made open to the public on 2 June 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/268766 |
| DOI(出版社版): | 10.1021/acs.orglett.1c01355 |
| PubMed ID: | 34076437 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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