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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.2c00084.pdf | 1.24 MB | Adobe PDF | 見る/開く |
| タイトル: | Reductive Ring Opening of Arylcyclopropanecarboxamides Accompanied by Borylation and Enolate Formation |
| 著者: | Wang, Shuo Kaga, Atsushi Kurogi, Takashi    https://orcid.org/0000-0002-8804-757X (unconfirmed)Yorimitsu, Hideki https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 王, 爍 加賀, 敦志 黒木, 尭 依光, 英樹 |
| キーワード: | Enolates Ring opening reactions Carbonyls Electrophiles Selectivity reduction cyclopropane metalation borylation enolate |
| 発行日: | Feb-2022 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Organic Letters |
| 巻: | 24 |
| 号: | 4 |
| 開始ページ: | 1105 |
| 終了ページ: | 1109 |
| 抄録: | Treatment of arylcyclopropanecarboxamides with a sodium dispersion in the presence of methoxypinacolborane as a reduction-resistant electrophile leads to reductive cleavage of the cyclopropane ring followed by instant trapping with the boron electrophile to yield the enolates of γ-aryl-γ-borylalkanamides. The enolates react further with a different electrophile to yield the corresponding α-substituted amides with anti selectivity. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.2c00084. The full-text file will be made open to the public on 25 January 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/268767 |
| DOI(出版社版): | 10.1021/acs.orglett.2c00084 |
| PubMed ID: | 35076241 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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