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タイトル: Effects of Regioregularity of pi-Conjugated Polymers Composed of Boron beta-Diketiminate on Their Stimuli-Responsive Luminescence
著者: Ito, Shunichiro  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-3822-0247 (unconfirmed)
Fukuyama, Misuzu
Tanaka, Kazuo  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-6571-7086 (unconfirmed)
Chujo, Yoshiki
著者名の別形: 伊藤, 峻一郎
福山, 美鈴
田中, 一生
中條, 善樹
キーワード: boron complexes
luminescence
pi-conjugated polymers
stimuli responsiveness
発行日: May-2022
出版者: Wiley
誌名: Macromolecular Chemistry and Physics
巻: 223
号: 9
論文番号: 2100504
抄録: π-Conjugated polymers composed of a boron β-diketiminate complex with different regioregularity are synthesized by using Suzuki–Miyaura and Yamamoto couplings. The films formed with the polymers show luminescence chromism upon exposure to solvent vapors. Most importantly, the chromic behavior depends on the regioregularity of the polymers. Wide-angle X-ray diffraction, thermal analysis, and density functional theory calculations suggest that the chromism can originate from the morphological change in the films and the alternation of the electronic nature of the main chains.
著作権等: This is the peer reviewed version of the following article: [Ito, S., Fukuyama, M., Tanaka, K. and Chujo, Y. (2022), Effects of Regioregularity of π-Conjugated Polymers Composed of Boron β-Diketiminate on Their Stimuli-Responsive Luminescence. Macromol. Chem. Phys., 223: 2100504.], which has been published in final form at https://doi.org/10.1002/macp.202100504. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
The full-text file will be made open to the public on 23 March 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/269610
DOI(出版社版): 10.1002/macp.202100504
出現コレクション:学術雑誌掲載論文等

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