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このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acsomega.1c05739.pdf | 1.7 MB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis and Oligomerization of CpM(CO)₂ |
| 著者: | Hashikawa, Yoshifumi    https://orcid.org/0000-0001-7834-9593 (unconfirmed)Murata, Yasujiro https://orcid.org/0000-0003-0287-0299 (unconfirmed) |
| 著者名の別形: | 橋川, 祥史 村田, 靖次郎 |
| キーワード: | Lipids Metals Crystal structure Oligomers Transition metals |
| 発行日: | Dec-2021 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | ACS Omega |
| 巻: | 6 |
| 号: | 49 |
| 開始ページ: | 34137 |
| 終了ページ: | 34141 |
| 抄録: | We showcase efficient synthetic protocols of cyclopentadienyl metal dicarbonyl, CpM(CO)₂ (M = Rh and Ir). Reflecting the relativistic effect, the ¹H and ¹³C signals of the Cp ring in CpIr(CO)₂ were upfield shifted when compared with the Rh analogue. A missing dinuclear complex, (CpIr)₂(μ-CO)(CO)₂, was spontaneously generated together with [CpIr(CO)]₃ by the loss of CO. The crystallographic analyses unambiguously determined their unique structures with one and three Ir–Ir bonds, respectively. |
| 著作権等: | Copyright © 2021 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial NoDerivative Works Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. |
| URI: | http://hdl.handle.net/2433/274619 |
| DOI(出版社版): | 10.1021/acsomega.1c05739 |
| PubMed ID: | 34926961 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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