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タイトル: | Influence of microstructural variations on morphology and separation properties of polybutadiene-based polyurethanes |
著者: | Pournaghshband Isfahani, Ali Shahrooz, Mahdi Yamamoto, Takuma Muchtar, Ansori Ito, Masateru M. Yamaguchi, Daisuke Takenaka, Mikihito https://orcid.org/0000-0002-6803-048X (unconfirmed) Sivaniah, Easan https://orcid.org/0000-0001-7293-8370 (unconfirmed) Ghalei, Behnam |
著者名の別形: | 山本, 拓磨 伊藤, 真陽 山口, 大輔 竹中, 幹人 |
発行日: | Apr-2021 |
出版者: | Royal Society of Chemistry (RSC) |
誌名: | RSC Advances |
巻: | 11 |
号: | 25 |
開始ページ: | 15449 |
終了ページ: | 15456 |
抄録: | Polybutadiene-based polyurethanes with different cis/trans/1, 2-vinyl microstructure contents are synthesized. The phase morphology and physical properties of the polymers are investigated using spectroscopic analysis (FTIR and Raman), differential scanning calorimetry (DSC), X-ray scattering (WAXD and SAXS) and atomic force microscopy (AFM). In addition, their gas transport properties are determined for different gases at 4 bar and 25 °C. Thermodynamic incompatibility and steric hindrance of pendant groups are the dominant factors affecting the morphology and properties of the PUs. FTIR spectra, DSC, and SAXS analysis reveal a higher extent of phase mixing in high vinyl-content PUs. Moreover, the SAXS analysis and AFM phase images indicate smaller microdomains by increasing the vinyl content. Smaller permeable soft domains as well as the lower phase separation of the PUs with higher vinyl content create more tortuous pathways for gas molecules and deteriorate the gas permeability of the membranes. |
著作権等: | © 2021 The Author(s). Published by the Royal Society of Chemistry This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. |
URI: | http://hdl.handle.net/2433/275722 |
DOI(出版社版): | 10.1039/d1ra00764e |
PubMed ID: | 35424034 |
出現コレクション: | 学術雑誌掲載論文等 |
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