ダウンロード数: 92
このアイテムのファイル:
ファイル | 記述 | サイズ | フォーマット | |
---|---|---|---|---|
acs.jpcc.2c04715.pdf | 1.42 MB | Adobe PDF | 見る/開く |
タイトル: | Concentrated Aqueous Solution of Chromium Dichloride for Chromium Metal Electrodeposition |
著者: | Matsumoto, Kazuhiko https://orcid.org/0000-0002-0770-9210 (unconfirmed) Zhang, Jingyuan Yoneda, Nozomi Numata, Koma Okuno, Kazuki Hagiwara, Rika https://orcid.org/0000-0002-7234-3980 (unconfirmed) |
著者名の別形: | 松本, 一彦 張, 靖遠 米田, 稀 萩原, 理加 |
キーワード: | Chromium metal Electrodeposition Concentrated solution Divalent High adhesion |
発行日: | 25-Aug-2022 |
出版者: | American Chemical Society (ACS) |
誌名: | The Journal of Physical Chemistry C |
巻: | 126 |
号: | 33 |
開始ページ: | 14346 |
終了ページ: | 14352 |
抄録: | Concentrated electrolytes have been found to play host to stellar phenomena previously unachievable in solutions at diluted or moderate concentrations. In an attempt to explore the possible utility of concentrated electrolytes in electroplating, this study reports the electrodeposition of Cr metal using a concentrated aqueous solution of Cr(II) (4.0 mol kg⁻¹) without additives. Target aqueous CrCl₂ solutions are characterized by UV–visible spectroscopic and ionic conductivity measurements. The influence of concentration, current density, and agitation on Cr metal deposition is discussed on the basis of cyclic voltammetry, galvanostatic electrolysis, X-ray diffraction, and scanning electron microscopy. Here, electrolysis of the concentrated electrolyte at medium current densities (20 mA cm⁻²) under agitation is found to engender dense metallic α-Cr deposits with high adhesivity to the substrate. The results further show that increasing the current density to expedite the deposition process promotes the involvement of an impurity phase and deposition of the δ-Cr phase. |
著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'The Journal of Physical Chemistry C', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpcc.2c04715. The full-text file will be made open to the public on 12 August 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/276137 |
DOI(出版社版): | 10.1021/acs.jpcc.2c04715 |
出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。