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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ejoc.202200567.pdf | 672.79 kB | Adobe PDF | 見る/開く |
| タイトル: | Catalytic Asymmetric Synthesis of 2,6‐Disubstituted Cuneanes via Enantioselective Constitutional Isomerization of 1,4‐Disubstituted Cubanes |
| 著者: | Takebe, Hiyori    https://orcid.org/0009-0000-8763-8389 (unconfirmed)Matsubara, Seijiro https://orcid.org/0000-0001-8484-4574 (unconfirmed) |
| 著者名の別形: | 竹邊, 日和 松原, 誠二郎 |
| キーワード: | Asymmetric Synthesis Chiral Scaffold Cuneane Cubane Pd-pincer |
| 発行日: | 7-Oct-2022 |
| 出版者: | Wiley |
| 誌名: | European Journal of Organic Chemistry |
| 巻: | 2022 |
| 号: | 37 |
| 論文番号: | e202200567 |
| 抄録: | 2, 6-Disubstituted cuneane has potential as a p -disubstituted benzene bioisostere and a novel chiral scaffold. It is a constitutional isomer of a 1, 4-disubstituted cubane obtained via a metal-catalyzed skeletal rearrangement. Unlike the highly symmetrical 1, 4-disubstituted cubane, the isomerized 2, 6-disubstituted cuneane is a chiral molecule possessing C 2 symmetry. Examining various chiral catalysts revealed that the Pd-pincer catalyst provides a good asymmetric induction. |
| 記述: | 【研究成果】正立方体型分子から六面体かご型分子へと骨格を変えることに成功. 京都大学プレスリリース. 2022-06-24. |
| 著作権等: | This is the peer reviewed version of the following article: [H. Takebe, S. Matsubara, Eur. J. Org. Chem. 2022, e202200567.], which has been published in final form at https://doi.org/10.1002/ejoc.202200567. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. The full-text file will be made open to the public on 11 July 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/276586 |
| DOI(出版社版): | 10.1002/ejoc.202200567 |
| 関連リンク: | https://www.t.kyoto-u.ac.jp/ja/news/topics/research/20220624 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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