Electrochemical Production of Silicon

Abstract

Silicon solar cells are crucial devices for generating renewable energy to promote the energy and environmental fields. Presently, high-purity silicon, which is employed in solar cells, is manufactured commercially via the Siemens process. This process is based on hydrogen reduction and/or the thermal decomposition of trichlorosilane gas. The electrochemical process of producing silicon has attracted enormous attention as an alternative to the existing Siemens process. Thus, this article reviews different scientific investigations of the electrochemical production of silicon by classifying them based on the employed principles (electrorefining, electrowinning, and solid-state reduction) and electrolytes (molten oxides, fluorides, chlorides, fluorides–chlorides, ionic liquids [ILs], and organic solvents). The features of the electrolytic production of silicon in each electrolyte, as well as the prospects, are discussed.