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electrochemistry.23-00025.pdf | 1.34 MB | Adobe PDF | 見る/開く |
タイトル: | Effects of Ion Fraction in an Inorganic Ionic Liquid Electrolyte on Performance of Intermediate-Temperature Operating Sodium-Sulfur Batteries |
著者: | WANG, Di HWANG, Jinkwang ![]() ![]() ![]() KUBOTA, Keigo MATSUMOTO, Kazuhiko ![]() ![]() ![]() HAGIWARA, Rika ![]() ![]() |
著者名の別形: | 黄, 珍光 松本, 一彦 萩原, 理加 |
キーワード: | Electrolyte Sodium-sulfur Batteries Inorganic Ionic Liquid Polysulfide Solubility |
発行日: | Apr-2023 |
出版者: | The Electrochemical Society of Japan |
誌名: | Electrochemistry |
巻: | 91 |
号: | 4 |
論文番号: | 047003 |
抄録: | Sodium-sulfur (Na-S) batteries are promising energy storage systems for renewable energy sources which redeem an intermittent energy source. This study reports the effects of the Na[SO₃CF₃] fraction in an inorganic Na[SO₃CF₃]-Cs[N(SO₂CF₃)₂] ionic liquid electrolyte (x(Na[SO₃CF₃]) = 0.2, 0.3, and 0.4) on the performance of Na-S batteries. Measurements of physicochemical and electrochemical properties demonstrated that decrease in the Na[SO₃CF₃] fraction decreases viscosity and increases ionic conductivity and the solubility of polysulfides into the ionic liquid, which contributes to the enhanced capacity in the low potential region during discharging. |
著作権等: | © The Author(s) 2023. Published by ECSJ. This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial-ShareAlike 4.0 License (CC BY-NC-SA, |
URI: | http://hdl.handle.net/2433/284861 |
DOI(出版社版): | 10.5796/electrochemistry.23-00025 |
出現コレクション: | 学術雑誌掲載論文等 |

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