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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ajoc.202300232.pdf | 383.06 kB | Adobe PDF | 見る/開く |
| タイトル: | Alkoxymigration onto alpha-Imino Gold Carbenes for Constructing Propellane-Type Indolines |
| 著者: | Greiner, Luca C. Arichi, Norihito    https://orcid.org/0000-0003-3618-4959 (unconfirmed)Inuki, Shinsuke https://orcid.org/0000-0002-7525-1280 (unconfirmed)Ohno, Hiroaki https://orcid.org/0000-0002-3246-4809 (unconfirmed) |
| 著者名の別形: | 有地, 法人 井貫, 晋輔 大野, 浩章 |
| キーワード: | Carbene Carboalkoxylation Gold catalysis Indoline Propellane |
| 発行日: | Jul-2023 |
| 出版者: | Wiley |
| 誌名: | Asian Journal of Organic Chemistry |
| 巻: | 12 |
| 号: | 7 |
| 論文番号: | e202300232 |
| 抄録: | We developed a new reaction entity of α-imino gold carbenes involving alkoxy migration. The reaction would proceed through oxonium ylide formation by intramolecular addition of an alkoxy group, carbon-oxygen bond cleavage, and carbon−carbon bond formation. We achieved an efficient gold-catalyzed synthesis of indoline-propellanes via a one-pot sequence by using ethylene glycol as a trapping reagent. |
| 著作権等: | his is the peer reviewed version of the following article: [Greiner, L. C., Arichi, N., Inuki, S., Ohno, H., Asian J. Org. Chem. 2023, 12, e202300232.], which has been published in final form at https://doi.org/10.1002/ajoc.202300232. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. The full-text file will be made open to the public on 30 June 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/284889 |
| DOI(出版社版): | 10.1002/ajoc.202300232 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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