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タイトル: Praseodymium Oxide Improving the Activity of a Silver-Loaded Calcium Titanate Photocatalyst for Carbon Dioxide Reduction with Water
著者: Qiu, Hongxuan
Anzai, Akihiko
Soltani, Tayyebeh
Yamamoto, Akira  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-1329-0807 (unconfirmed)
Fudo, Eri
Tanaka, Atsuhiro
Kominami, Hiroshi
Yoshida, Hisao  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-2540-0225 (unconfirmed)
著者名の別形: 仇, 宏暄
安齋, 亮彦
山本, 旭
吉田, 寿雄
キーワード: photocatalytic CO₂ reduction
CO formation
calcium titanate photocatalyst
different calcination temperatures
Ag cocatalyst
Pr₆O₁₁
発行日: 22-May-2023
出版者: American Chemical Society (ACS)
誌名: ACS Applied Energy Materials
巻: 6
号: 10
開始ページ: 5396
終了ページ: 5406
抄録: Heterogeneous photocatalytic CO₂ reduction with water has attracted great attention. Although the addition of Ag nanoparticles (NPs) as a cocatalyst on a semiconductor photocatalyst has been known to improve both the photocatalytic activity and reaction selectivity for CO₂ reduction, the addition of Pr as Pr₆O₁₁ species on the surface of an Ag-loaded CaTiO₃ (CTO) photocatalyst further improved the photocatalytic activity. The different calcination temperatures for the sample preparation changed the state of Pr species, and it strongly influenced the photocatalytic performance. The Pr₆O₁₁ species was found to be loaded between the CTO surface and Ag NPs on the Ag/Pr/CTO photocatalyst, proposing that it improves the electron migration from the CTO photocatalyst to Ag NPs via the Pr₆O₁₁ layer.
著作権等: This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Energy Materials, Copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsaem.3c00476.
The full-text file will be made open to the public on May 12, 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/285042
DOI(出版社版): 10.1021/acsaem.3c00476
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