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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.3c02815.pdf | 1.38 MB | Adobe PDF | 見る/開く |
| タイトル: | An Unsymmetrical 5,15-Disubstituted Tetrabenzoporphyrin: Effect of Molecular Symmetry on the Packing Structure and Charge Transporting Property |
| 著者: | Miyazaki, Kazuya Matsuo, Kyohei   https://orcid.org/0000-0002-2472-9459 (unconfirmed)Hayashi, Hironobu Yamauchi, Mitsuaki  https://orcid.org/0000-0003-0005-5960 (unconfirmed)Aratani, Naoki Yamada, Hiroko https://orcid.org/0000-0002-2138-5902 (unconfirmed) |
| 著者名の別形: | 松尾, 恭平 山内, 光陽 山田, 容子 |
| キーワード: | Crystal structure Crystals Mobility Molecular structure Reaction products |
| 発行日: | 13-Oct-2023 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Organic Letters |
| 巻: | 25 |
| 号: | 40 |
| 開始ページ: | 7354 |
| 終了ページ: | 7358 |
| 抄録: | Molecular design strategy to control the crystal structure of two-dimensional (2D) 𝝅-extended organic semiconductors has not been intensively explored. We synthesized an unsymmetric tetrabenzoporphyrin derivative (TIPS-Ph-BP) to demonstrate the effect of molecular symmetry on crystal packing. TIPS-Ph-BP formed an antiparallel slipped 𝝅-stacking and 2D herringbone-like structure. An unsymmetric structure would make 2D 𝝅-stacking more stable than a one-dimensional (1D) columnar structure to counteract steric and electronic imbalance in the crystal. As a result, TIPS-Ph-BP achieved the high hole mobility of 0.71 ㎝² V⁻¹ s⁻¹. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Organic Letters', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.3c02815. The full-text file will be made open to the public on 29 September 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/285766 |
| DOI(出版社版): | 10.1021/acs.orglett.3c02815 |
| PubMed ID: | 37772724 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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