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タイトル: | Synthesis, cation exchange, and optical properties of pyrene-based chromophores containing [CB₉H₉]⁻ and [CB₁₁H₁₁]⁻ cluster units |
著者: | Ochi, Junki ![]() ![]() ![]() Yanagihara, Takumi Tanaka, Kazuo ![]() ![]() Chujo, Yoshiki |
著者名の別形: | 越智, 純毅 柳原, 拓海 田中, 一生 中條, 善樹 |
キーワード: | carborane ionic compound solid-state emission |
発行日: | Jan-2024 |
出版者: | Oxford University Press (OUP) |
誌名: | Bulletin of the Chemical Society of Japan |
巻: | 97 |
号: | 1 |
論文番号: | uoae005 |
抄録: | Four monocarborane anion-based compounds connected to a pyrene moiety were synthesized by combining two monocarborane anion scaffolds and two counter cations. The effects of the cage structure and the counter cation on the optical properties were investigated from UV-vis absorption and photoluminescence (PL) measurements. The PL spectra in the solid state were unique for each compound, derived from the different shapes of the carborane cage and counter cation. These results suggest great potential for designing a monocarborane anion-based chromophore. |
著作権等: | This is a pre-copyedited, author-produced version of an article accepted for publication in [Bulletin of the Chemical Society of Japan] following peer review. The version of record [Junki Ochi, Takumi Yanagihara, Kazuo Tanaka, Yoshiki Chujo, Synthesis, cation exchange, and optical properties of pyrene-based chromophores containing [CB₉H₉]⁻ and [CB₁₁H₁₁]⁻ cluster units, Bulletin of the Chemical Society of Japan, Volume 97, Issue 1, January 2024, uoae005, ] is available online at: https://doi.org/10.1093/bulcsj/uoae005 The full-text file will be made open to the public on 03 February 2025 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/287123 |
DOI(出版社版): | 10.1093/bulcsj/uoae005 |
出現コレクション: | 学術雑誌掲載論文等 |

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