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j.polymer.2024.127131.pdf1.35 MBAdobe PDF見る/開く
タイトル: Polymer crystallization process at high supercooling: Crystallization with nodular aggregation region near the glass transition
著者: Konishi, Takashi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-1134-5445 (unconfirmed)
Miyamoto, Yoshihisa
著者名の別形: 小西, 隆士
宮本, 嘉久
キーワード: Polymer crystallization
Aggregation
Crystalline nodular structure
Mesophase
Small angle X-ray scattering
Hierarchical structure
発行日: 3-Jun-2024
出版者: Elsevier BV
誌名: Polymer
巻: 304
論文番号: 127131
抄録: Polymer crystallization has been treated as the formation mechanism of lamellae based on secondary nucleation. This treatment has well explained many experimental results especially at a low supercooling. On the other hand, it is also known that some experimental results cannot be fully explained by this model when the degree of supercooling is large. This Feature Article reviews our recent studies on polymer crystallization at a high supercooling. We have revealed the evidence of the crystallization process through the mesophase at a higher supercooling. In addition, we have found the crystallization process with the nodular aggregation near the glass transition temperature. These processes are of great interest for the understanding of polymer crystallization.
著作権等: © 2024 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license.
URI: http://hdl.handle.net/2433/290098
DOI(出版社版): 10.1016/j.polymer.2024.127131
出現コレクション:学術雑誌掲載論文等

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