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タイトル: Surface Modifications of Heterogeneous Photocatalysts for Photocatalytic Conversion of CO₂ by H₂O as the Electron Donor
著者: Nakamoto, Takechi
Iguchi, Shoji  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-2522-1358 (unconfirmed)
Naniwa, Shimpei
Tanaka, Tsunehiro
Teramura, Kentaro  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-2916-4597 (unconfirmed)
著者名の別形: 中本, 嵩市
井口, 翔之
浪花, 晋平
田中, 庸裕
寺村, 謙太郎
キーワード: Photocatalysis
Heterogeneous catalysis
Photocatalytic conversion of CO₂ by H₂O
Surface modification
Cocatalyst
発行日: 25-Nov-2024
出版者: Wiley
誌名: ChemCatChem
巻: 16
号: 22
論文番号: e202400594
抄録: The photocatalytic conversion of CO₂ using H₂O over heterogeneous photocatalysts has attracted worldwide attention because it enables direct solar-to-chemical energy conversion. However, further development of this technology requires solutions to overcome the low formation rates of CO₂ reduction products and their insufficient selectivity, mainly caused by the rapid charge recombination of photogenerated electron/hole pairs, competition for thermodynamically preferential H₂ evolution from H₂O, and the relatively low concentration of CO₂ on the surface of the photocatalysts. Surface modification of heterogeneous photocatalysts is crucial for improving their formation rates and selectivity. This review article introduces four strategies for designing photocatalyst surfaces for the photocatalytic conversion of CO₂ by H₂O: (I) loading of an Ag cocatalyst, (II) utilisation of cocatalysts for H₂O oxidation, (III) suppression of undesired H₂ evolution, and (IV) loading of basic materials for CO₂ adsorption. The strategies introduced in this review successfully enhanced the formation rates of the products and/or their selectivity in the heterogeneous photocatalytic conversion of CO₂ by H₂O.
著作権等: © 2024 The Authors. ChemCatChem published by Wiley-VCH GmbH
This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
URI: http://hdl.handle.net/2433/290624
DOI(出版社版): 10.1002/cctc.202400594
出現コレクション:学術雑誌掲載論文等

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