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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acscatal.3c01504.pdf | 9.79 MB | Adobe PDF | 見る/開く |
| タイトル: | Utilization of Silanols in Transition Metal-Catalyzed Organic Synthesis |
| 著者: | Yamagishi, Hiroki Shimokawa, Jun    https://orcid.org/0000-0002-4023-4640 (unconfirmed)Yorimitsu, Hideki https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 山岸, 拓幹 下川, 淳 依光, 英樹 |
| キーワード: | silanol silanolate transition metal directing group organosilane coupling |
| 発行日: | 2-Jun-2023 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | ACS Catalysis |
| 巻: | 13 |
| 号: | 11 |
| 開始ページ: | 7472 |
| 終了ページ: | 7487 |
| 抄録: | The multifaceted implementation of silanols in organic synthesis is reviewed from the standpoint of developments in transition metal-catalyzed reactions. The major properties of silanols are summarized according to the research fields that have utilized these intriguing species: silanols as nucleophiles to serve as bulky surrogates for water; silanols as temporary ligands to control regioselectivity of metal-catalyzed reactions; silanols as coupling partners for transferring functional groups. These topics are summarized to provide opportunities for future developments in the chemistry of silanols. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], Copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.3c01504 The full-text file will be made open to the public on May 19, 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/293439 |
| DOI(出版社版): | 10.1021/acscatal.3c01504 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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