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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.4c01370.pdf | 701.21 kB | Adobe PDF | 見る/開く |
| タイトル: | Cobalt/Photoredox Dual-Catalyzed Cross-Radical Coupling of Alkenes via Hydrogen Atom Transfer and Homolytic Substitution |
| 著者: | Yamaguchi, Yuto Hirata, Yuki Higashida, Kosuke Yoshino, Tatsuhiko    https://orcid.org/0000-0001-9441-9272 (unconfirmed)Matsunaga, Shigeki https://orcid.org/0000-0003-4136-3548 (unconfirmed) |
| 著者名の別形: | 山口, 優冬 平田, 裕己 東田, 皓介 吉野, 達彦 松永, 茂樹 |
| キーワード: | Anions Catalysis Catalysts Hydrocarbons Redox reactions |
| 発行日: | 14-Jun-2024 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Organic Letters |
| 巻: | 26 |
| 号: | 23 |
| 開始ページ: | 4893 |
| 終了ページ: | 4897 |
| 抄録: | Cobalt-catalyzed metal hydride hydrogen atom transfer (MHAT) in combination with photoredox catalysis has emerged as a powerful synthetic method, owing to its redox nature and applicability to various radical precursors. Herein, we describe a cross-radical coupling reaction under cobalt/photoredox dual catalysis. MHAT and homolytic substitution (SH2) processes enabled Markovnikov-selective hydrobenzylation of di/trisubstituted alkenes, affording products with a quaternary carbon center in a redox-neutral manner. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], Copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.4c01370 The full-text file will be made open to the public on June 5, 2025 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/294414 |
| DOI(出版社版): | 10.1021/acs.orglett.4c01370 |
| PubMed ID: | 38836750 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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