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Title: Studies on explosion reaction of monovinyl acetylene gas : IV. Thermal reaction of monovinyl acetylene-oxygen mixture
Authors: Ikegami, Tatsuya
Issue Date: 1963
Publisher: The Physico-Chemical Society of Japan
Journal title: The Review of Physical Chemistry of Japan
Volume: 33
Issue: 2
Start page: 65
End page: 79
Abstract: The thermal reaction of monovinyl acetylene (MVA)-oxygen mixture was mainly studied at 250~400℃ and 230~400mmHg in the range of 3~17% of oxygen, and was referred simply to the range of large amounts of oxygen (40~60% 0_2). The reaction was complex and consisted of polymerization, decomposition and oxidation. Among them the reaction of oxidation was first order with respect to MVA and oxygen. Formaldehyde, as the organic oxide, in the gaseous products was found alone. The reaction mechanism was drawn with the assumption of the formation of MVA peroxide and polymeric MVA peroxide in the initial step.
Appears in Collections:Vol.33 No.2

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