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dc.contributor.authorIkegami, Tatsuyaja
dc.contributor.transcriptionイケガミ, タツヤja
dc.date.accessioned2007-09-10T06:44:23Z-
dc.date.available2007-09-10T06:44:23Z-
dc.date.issued1963ja
dc.identifier.issn0034-6675ja
dc.identifier.urihttp://hdl.handle.net/2433/46837-
dc.description.abstractThe thermal reaction of monovinyl acetylene (MVA)-oxygen mixture was mainly studied at 250~400℃ and 230~400mmHg in the range of 3~17% of oxygen, and was referred simply to the range of large amounts of oxygen (40~60% 0_2). The reaction was complex and consisted of polymerization, decomposition and oxidation. Among them the reaction of oxidation was first order with respect to MVA and oxygen. Formaldehyde, as the organic oxide, in the gaseous products was found alone. The reaction mechanism was drawn with the assumption of the formation of MVA peroxide and polymeric MVA peroxide in the initial step.ja
dc.language.isoengja
dc.publisherThe Physico-Chemical Society of Japanja
dc.titleStudies on explosion reaction of monovinyl acetylene gas : IV. Thermal reaction of monovinyl acetylene-oxygen mixtureja
dc.type.niitypeDepartmental Bulletin Paperja
dc.identifier.ncidAA00817661ja
dc.identifier.jtitleThe Review of Physical Chemistry of Japanja
dc.identifier.volume33ja
dc.identifier.issue2ja
dc.identifier.spage65ja
dc.identifier.epage79ja
dc.textversionpublisherja
dc.sortkey004ja
Appears in Collections:Vol.33 No.2

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