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Title: Effect of pressure on the dissociation of electrolytic solution : II. Effect of pressure on the migration of hexammine cobalt (III) ion in water
Authors: Osugi, Jiro
Shimizu, Kiyoshi
Takizawa, Hideto
Issue Date: 20-Jun-1965
Publisher: The Physico-Chemical Society of Japan
Journal title: The Review of Physical Chemistry of Japan
Volume: 34
Issue: 2
Start page: 55
End page: 58
Abstract: The pressure coefficients of the limiting ionic conductivity of [Co(NH_3)_6]^3+, SO_4^2-, Cl^- and K^+ in water at 25℃ have been obtained over the pressure range 1~600kg/cm^2. The results are used to evalute the volume of activation. ΔV≠, for ionic migration derived by applying the theory of transition state to the migration of an ion. For each ion ΔV≠ is negative and becomes less negative with increasing pressure, which may be due to the nature of water as solvent.
URI: http://hdl.handle.net/2433/46849
Appears in Collections:Vol.34 No.2

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