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dc.contributor.authorTanaka, Fujioja
dc.contributor.authorSasaki, Muneoja
dc.contributor.authorOsugi, Jiroja
dc.contributor.transcriptionタナカ, フジオja
dc.contributor.transcriptionササキ, ムネオja
dc.contributor.transcriptionオオスギ, ジロウja
dc.date.accessioned2007-09-10T06:46:56Z-
dc.date.available2007-09-10T06:46:56Z-
dc.date.issued1972-03-31ja
dc.identifier.issn0034-6675ja
dc.identifier.urihttp://hdl.handle.net/2433/46958-
dc.description.abstractAIBN was photolyzed in toluene at room temperature at pressures up to 2, 000kg/cm^2 and the rates of the disappearance of DPPH which was used as a radical scavenger were measured spectrophotometrically. The rate was decreased with increasing pressure and the apparent activation volume was +7.6cm^3/mole. In comparison with Ewald's results on the thermal dissociation of AIBN, it was considered that an important contribution to the apparent activation volume was due to the change of "cage efect" by plessure and that the retarding effect of pressure on the photodissociation of AIBN would be smaller than on the thermal dissociation of AIBN.ja
dc.language.isoengja
dc.publisherThe Physico-Chemical Society of Japanja
dc.titleEffect of pressure on the photolysis of azo-bis-isobutyronitrile in the presence of diphenylpicrylhydrazylja
dc.type.niitypeDepartmental Bulletin Paperja
dc.identifier.ncidAA00817661ja
dc.identifier.jtitleThe Review of Physical Chemistry of Japanja
dc.identifier.volume41ja
dc.identifier.issue1/2ja
dc.identifier.spage18ja
dc.identifier.epage21ja
dc.textversionpublisherja
dc.sortkey003ja
Appears in Collections:Vol.41 No.1 & 2

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