Access count of this item: 247

Files in This Item:
File Description SizeFormat 
rpcjpnv44p065.pdf1.93 MBAdobe PDFView/Open
Title: Pressure effect on intersystem crossing from the first excited singlet state of anthracene and its derivatives in solution
Authors: Tanaka, Fujio
Issue Date: 30-Apr-1975
Publisher: The Physico-Chemical Society of Japan
Journal title: The Review of Physical Chemistry of Japan
Volume: 44
Issue: 2
Start page: 65
End page: 76
Abstract: The fluorescence yields of anthracene and its derivatives have been measured in several solvents at room temperature up to 3000kg/cm^2, The solvent and pressure effects on the intersystem crossing rates (ki.) have been interpreted in view of changes in the Franck-Condon factors due to variations in the S_1-T_2 energy gap. The previously presented idea that ki, varies with the changes in the S_1-T_2 energy gap in correspondence to a vibrational structure of the Franck-Condon factor between S_1 and T_2 has been supported by the present results though somewhat qualitatively. The deuteration effects on ki, have also been investigated from similar standpoints.
URI: http://hdl.handle.net/2433/47000
Appears in Collections:Vol.44 No.2

Show full item record

Export to RefWorks


Export Format: 


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.