Contributions of steady heat conduction to the rate of chemical reaction

Abstract

We have derived the effect of steady heat flux on the rate of chemical reaction based on the line-of-centers model using the explicit velocity distribution function of the steady-state Boltzmann equation for hard-sphere molecules to second order. It is found that the second-order velocity distribution function plays an essential role for the calculation of it. We have also compared our result with those from the steady-state Bhatnagar–Gross–Krook (BGK) equation and information theory, and found no qualitative differences among them.