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Title: Contributions of steady heat conduction to the rate of chemical reaction
Authors: Kim, Hyeon-Deuk  kyouindb  KAKEN_id
Hayakawa, Hisao  kyouindb  KAKEN_id
Author's alias: 金, 賢得
早川, 尚男
Issue Date: Apr-2003
Publisher: Elsevier
Journal title: Chemical Physics Letters
Volume: 372
Issue: 3-4
Start page: 314
End page: 319
Abstract: We have derived the effect of steady heat flux on the rate of chemical reaction based on the line-of-centers model using the explicit velocity distribution function of the steady-state Boltzmann equation for hard-sphere molecules to second order. It is found that the second-order velocity distribution function plays an essential role for the calculation of it. We have also compared our result with those from the steady-state Bhatnagar–Gross–Krook (BGK) equation and information theory, and found no qualitative differences among them.
Rights: Copyright © 2004 Elsevier B.V. All rights reserved.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/49789
DOI(Published Version): 10.1016/S0009-2614(03)00367-1
Appears in Collections:Journal Articles

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