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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| v3-p30.pdf | 43.22 kB | Adobe PDF | 見る/開く |
| タイトル: | Mechanism and Kinetics of Nitroxide-Controlled Free Radical Polymerization (ORGANIC MATERIALS CHEMISTRY-Polymeric Materials) |
| 著者: | Fukuda, Takeshi Tsujii, Yoshinobu    https://orcid.org/0000-0002-4357-6902 (unconfirmed)Miyamoto, Takeaki |
| キーワード: | Nitroxyl-polymer adduct Reversible dissociation Initiation Termination Decomposition Narrow polydispersity |
| 発行日: | Mar-1997 |
| 出版者: | Institute for Chemical Research, Kyoto University |
| 誌名: | ICR Annual Report |
| 巻: | 3 |
| 開始ページ: | 30 |
| 終了ページ: | 31 |
| 抄録: | In the nitroxide-mediated free radical polymerization, the rate of polymerization is determined by the balance of the rates of thermal initiation and bialkyl termination, just like in the conventional system, while the polydispersity is determined by the dissociation-combination frequency of the polymer-nitroxyl adduct and the rate of decomposition of the adduct. These mechanisms were quantitatively confirmed by both experiments and computer simulations. |
| URI: | http://hdl.handle.net/2433/65111 |
| 出現コレクション: | Vol.3 (1996) |
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