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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| v3-p14.pdf | 62.08 kB | Adobe PDF | 見る/開く |
| タイトル: | Molecular Design of Chelating Ligands with Highly Selective Recognition and Separation Functions for Group 13 Metal Ions (INTERFACE SCIENCE-Separation Chemistry) |
| 著者: | Umetani, Shigeo Le, Quyen T. H. Matsui, Masakazu |
| キーワード: | Solvent extraction b-Diketone Acylpyrazolone Molecular recognition Substituent effect Bite size Interligand contact |
| 発行日: | Mar-1997 |
| 出版者: | Institute for Chemical Research, Kyoto University |
| 誌名: | ICR Annual Report |
| 巻: | 3 |
| 開始ページ: | 14 |
| 終了ページ: | 15 |
| 抄録: | Highly selective ligands for group 13 metal ions (Al3+, Ga3+ and In3+) have been successfully designed taking into consideration the bite size (O-O distance in the chelate ring) and the interligand contact in the complex. The complexation of Al3+ was found to be under the effect of the interligand contact and that of In3+ the bite size. The appropriate substituents were introduced to b-diketone type ligands to control the bite size and the volume of the ligand. |
| URI: | http://hdl.handle.net/2433/65120 |
| 出現コレクション: | Vol.3 (1996) |
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